Selective epoxidation of olefines using dioxirane system
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Authors
Rosebraugh, Matthew
Cole, Erin
Mirafzal, Gholam A.
Issue Date
2007-05-31T20:04:54Z
Type
Presentation
Language
en_US
Keywords
Organic chemistry , Epoxy compounds , Epoxide , Oxone , Dioxirane
Alternative Title
Abstract
Oxidation of alkenes using 1,3-dichloromethyldioxirane produces good to excellent yield of epoxide products. The reaction system is facile, mild, efficient and safe. Our results involving epoxidation of various alkene substrates with different degree of ionizibilities, along with our studies involving selectivity experiments in 1:1 competitive alkenes epoxidation reactions will be presented.